I could be wrong here, but my point was that, currently we do not have technology to study an exoplanet that way. Our spectroscopic analysis is limited to planets in our solar system and stars.
As I said, I can be wrong, so I will try to find out more on this and will get back.
We CAN actually study atmospheric composition and other properties of extra solar planets by spectral analysis. As Developereo mentioned, it can only be done when the planet makes a transit in front of the planet.
Here is an excellent source for you

http://arxiv.org/PS_cache/astro-ph/pdf/0603/0603376v1.pdf
Composition of the atmosphere of many exoplanets have been found this way


but as far as the question of any intelligent life like us out there in the universe is concerned then i guess we humans (as intelligent beings) are unique in this universe:
